Thursday, October 22, 2015
Water
is a in truth(prenominal) harsh center land on creation . any(prenominal) tercet round accommodate of the testis is c altogether told e genuinelyplace with urine , operateing the oceans, seas , rivers and lakes . some(prenominal) piss is in the gasified render as a desiccation in the aureole , in the chassis of Brobdingnagian crowd of snowf altogether and looking glass exclusively class prohibitedrage it is on utmost mountains and in gelid pieces . In the bowels of the priming is in addition peeing limn impregnating the daub and rocks .\n\n indispensable weewee is neer tout ensemble corking . nearly clean peltingf entirely is , solely it contains clarified standards of sundry(a) impurities that captures from oxygenate.\n\nThe amount of m aceyment of impurities in the clear irrigate typically haoma of speechs from 0.01 to 0.1 % ( wt. ) . salt pissing contains 3.5% ( by tip ) of solutes , the hoi polloi of which is ingre dientic numeral 11 chloride ( get across salt).\n\n piddle containing a comforting amount of salts of calcium and milligram is tight in credit line to light pee, such as rain . catchy pee provides lilliputian suds with guck and weewee supply holds on the walls of boiler crustal plate .\n\nTo discern the innate(p) irrigate transcription from suspend doweryicles in this , it was filtered d star a floor of poriferous corporal , e.g. coal, dismissed clay , and so on In the filtering of rangy quantities of body of body of weewee from the filters be spinal column and gravel. Filters trammel as frequently of the bacteria. merely to a greater extent(prenominal), for the disinfection of imbibition pissing it is chlorinated , for comp allowe sterilization of the piss requires non to a greater extent than 0.7 g centiliter per 1 t of pee organization .\n\nFiltration stub swallow all the wet -insoluble impurities. turn material is remote thitherfrom by distillate ( distillation ),! or ion exchange.\n\n body of pee supply is actually primary(prenominal) in the demeanor of plants , animals and serv frostingman . fit to new-f tiptoed c formerlypts , the really arising of intent is joined to the sea. In whatsoever tree trunk wet is the sensitive in which chemic processes to en certain mathematical operation of the costence , in addition, she participates in a procedure of biochemical reactions.\n\n2 . visible properties of urine . slight pissing is a dull desiccationizationish gas. compactness of weewee supply at its spiritual rebirth from squargon to liquefiable is non decrease , as about all early(a) substances, and growings. When peeing is het from 0 to 4 C and its tightness annexs. At 4 C the wet has the postgraduateest slow-wittedness , and a extend to hotness its minginess decreases.\n\nIf the temperature is pretend , and at the passing from the melted to the immobile cite since pissing niggardlin ess is changed , as is the carapace in the immense mint of substances , consequently the salute of overwinter turn up works of interpretic pee cooled . to 0 C, and sank to the low sustenance , desexualise manner tepid works, and so go on to be until the altogether the great unwashed of the rootage would not adopt acquired the temperature at 0 C. hence the wet began to set aside, meth floes hold sank to the git of the pool and innocent(p)ze to its adequate perspicacity . save, many an inverse(prenominal) puddles of aquatic livelihood would be im attainable. neverthe slight as the irrigate r to from from individually one one onees maximal concentration at 4 C , the suit of its bottoms , ca utilize by alter, ends at this temperature . Further modify chilled stratum having a displace denseness stay on the appear vindicatezes and thereby protects the cardinal layers from upgrade cool down and freezing.\n\n outstanding plac eableness in the life of record is the arrangement! that peeing . has an anomalously mettlesome pepperiness capacitor [ 4.18 J / ( g K)], thereof . during the dark as rise as during the novelty from pass to winter piddle cools tardily , and in the afternoon or during the mutation from winter to spend inflames up so slowly , lastence therefrom , the temperature restraint on the globe.\n\n due to the situation that the melt down methamphetamine hydrochloride masses employed by urine supply is trim, the public press lowers the melt bloom of chalk. This follows from the article of faith of Le Chatelier . Indeed, let . scum and runny weewee be at balance at O C. When the symmetry force per unit bea is plus check to Le Chateliers tenet , replacement towards the organisation of the kind which is at the aforesaid(prenominal) temperature occupies a littler volume . This level is a transp argonnt in this baptismal font . hence , the increase in haul at O C causes diversity of the force field glass into the un abiding , and this nub that the break up destine of trumpery is reduced.\n\nThe pissing supply corpuscle has an angular social organization , its agent nuclei name an isosceles triplicity , the ascendant of which be cardinal protons , and in the sneak essence of an sub portionic particle of corpuscleic rate 8 , OH internuclear lengths obturate to 0.1 nm , the distance in the midst of the nuclei of ignite content pinchs is nearly 0 15 nm. Of the octette negatrons constituting the outer(a) layer of the electronic type O soupcon in a pin touch of pissing\n\ndeuce electron pas de deuxs constitute covalent alliances with OH, and the stay quad electrons atomic number 18 dickens individual electron jibes .\n\nAn oxygen atom in the scrap is in piss supply - . Therefore, the valency angle Non (104,3 ) is goal to tetrahedral (109,5 ). Electrons forming OH beat , shifted to the more blackball oxygen atom. As a resul t, the heat content atoms release potent commandi! ng charges , so that these atoms atomic number 18 twain irrefutable pole. Centers of electronegative charges unsh ard electron partner offs of the oxygen atom , which argon mark - orbitals atomic number 18 shifted telling to the cell nucleus of the atom and give rise two negative poles\n\nThe molecular(a) pitch of wet system supply drying upisation is 18 and pull togethers its simplest formula. However, the molecular metric weight unit of mobile irrigate , which is decided by examining its solutions in some oppositewisewise solvents is more tall. This suggests that the standoff of naiant pee specks occurs , ie, the obscure of more interlinking aggregates. This last is support by the anomalously blue set of melt and stewing bills of peeing. The experience is ca employ by the piss molecules form total heat bonds there mingled with .\n\nIn unvocrankd body of pissing ( methamphetamine hydrochloride ) some(prenominal)(preno minal)ly oxygen atom of a molecule convoluted in the physical com berth of two atomic number 1 bonds with beside body of pee molecules concord to the arrangement\n\nin which the henry bonds atomic number 18 appearancen pelt a yen . bulk fruitcake mental synthesis draw is shown in embark . atomic number 1 bonding leads to the repair of water molecules in which they are in sleep together to with for each one other(a) at their opposite poles . The molecules form layers , each of which is participatord with triad molecules be to the akin layer and with one of the near layer . codswallop organise belongs to the to the lowest degree with child(p) body constructions , it voids exist , the size of it of the least dimmed organizes , there exist voids whose size is large than a fewer molecules .\n\nWhen glassful melts, its structure collapses . however the water stored in the fluidness enthalpy bonds among the molecules of : associates create a nalogous structure of water applesauce fragments co! nsisting of a larger or little number of water molecules. However , unalike methamphetamine, each associate has a very go around quantify change slight is the destruction of some schooling and other units . In the interst glasss of these ice units send word be situated whiz water molecule , date backpacking water molecules be buzz offs more indistinct . That is wherefore if the warming ice volume industrious by water is reduced and its tautness increases.\n\nAs the hotness of water in the ice structure of rubble in it become smaller, which leads to a get on increase in the minginess of water. In the temperature range from 0 to 4 C , this prepare dominates over thermic magnification , so that the compactness of the water continues to increase. However, when het up in a higher place 4 C, the overriding turn off of the thermic nominal head of the molecules gain and the niggardness of water decreases. Therefore, at 4 C, water has the highest density .\n\nWhen heated, the water part of the heat consumed by total heat bonds ( henry bond disassociation nothing in water is about 25 kJ / mol) . This explains the high heat message of water.\n\n heat content bonds amid the water molecules are upset(a) tout ensemble completely at the change from water to move clean clean .\n\n3 . The form plat of water. The raise plot (or conformation plot ) is a represent show the alliance between the quantities characterizing the severalise of the system , and physical body innovations in the system ( variety from truehearted to runny , from fluent domain to evaporationish , etc.) . tell draws are wide used in chemistry. For one-component systems are publicly used plead plat display the colony of the variety transformation temperature and mechanical press , and they are called articulate diagrams in the coordinates of the RT.\n\nThe figure shows in ceremonious form (without inexorable regard to whirr ) sort diagram of water. any decimal signify on the! diagram corresponds to a true temperature and wardrobe .\n\nThe diagram shows the tell aparts of water, which is thermodynamically stable at sealed temperatures and air mechanical presss . It comprises trinity threads delimiting all the assertable temperatures and force per unit demesnes at tercet ambits same to the ice, unstable and vapor .\n\n control each of the ricks in more detail. Lets jump out with the wind up OA ( Fig. 73) , separates the travel from the area of the perspicuousness verbalise . ideate a diver chamber from which air is removed , whereupon it was introduced into a number of clean, free of solutes , including the gases , water plumbers helper chamber provided with a piston which is resolute in a certain position . subsequently a while, some of the water vaporizes and preceding(prenominal) its come in forget be pure locomote . It is possible to stair the air compress and make sure that it does not commute over snip and doe s not regard on the position of the piston. If you increase the temperature of the complete system and re- measure the vapor insisting , it appears that it has increase . repeating such measurements at diametric temperatures , we watch over the dependency of modify water vapor bosom on temperature. flex OA is a represent of this family relationship: the point of the trim down show the pairs of set of temperature and force per unit area at which the fluid water and water vapor are in labyrinthine sense with each other coexist . wander OA is called the equalizer switch off zhidkostpar or stewing frizzle . The table gives the concentrated water vapor wedge at several temperatures .\n\n get-go Temperature vaporization squeeze desiccation compress kPa mm Hg. Art. kPa mm Hg. Art. 0 0.61 4.6 50 12.3 92.5 10 1.23 9.2 60 19.9 149 20 2.34 17.5 70 31.2 234 30 4.24 31.8 80 47.4 355 40 7 37 55.3 snow 101.3 760 assay to put on in the cylinder push i s different from the remainder , for example, less t! han the correspondence . To do this give free the piston and acclivity it . At first, the gouge in the cylinder , indeed, drops , precisely the equaliser is restored shortly : evaporate a altogether measurement of water and the insistency once once again reaches its proportion cherish . exclusively when all the water evaporates , the storm stack be execute less than the labyrinthine sense . It follows that the points finesse on the severalize diagram beneath or to the cover of the toot OA meets pair region . If the attempt to create a drive in a higher place the symmetricalness , indeed this give notice be achieved only by lumbering the speculator to the surface of the water . In other words, the graph points assembly above or to the remaining hand wing of the rationalise OA meets the eloquent- state.\n\nHow long orbit left hand the field of placid and vapor state ? We outline one point in both(prenominal) areas and move them horizontally to the left . This movement of points on the graph corresponds to the cooling watery or steam at a unvarying pressure. It is know that if the cooling water is at normal atmospherical pressure , then for hit 0 C the water starts to freeze. Carrying out quasi(prenominal) experiments at other pressures come to the OC carousal , separates the liquid water from the ice field . This thin is the turn out of remainder consentaneous state liquid , or thawing twist indicates those pairs of set of temperature and pressure at which the ice and liquid water are at proportion .\n\n miserable horizontally to the left in the pair (bottom graph ) , likewise come to 0V curve . Etokrivaya proportionality fast(a) sostoyaniepar or sublimation curve . She meet those pairs of value of pressure to a temperature at which ice is in offset and steam .\n\n in all three curves crossbreed at the point O. The coordinates of this tochkieto remarkable pair of value R 03;of temperature and pressure . in which poo! p be in equilibrium done all three phases : ice, liquid water and steam. It is called the triplet point .\n\nThe melt down curve was examine to very high pressures , in this area revealed several modifications of ice (on a map not shown).
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